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Freon is DuPont's trade name for its odorless, colorless, nonflammable, and noncorrosive chlorofluorocarbon and hydrochlorofluorocarbon refrigerants, which are used in air conditioning, refrigeration and some automatic fire-fighting systems. It is one of a class of chemicals called Haloalkanes; Freon and similar refrigerants have been controversial due to environmental and safety concerns. Breathing any amount of Freon is safe, but when the amount of Freon in the air is so high that there is not enough oxygen, asphyxiation can result.¹²

History

Freon was initially developed in the early 20th century as an alternative to the toxic gases that were previously used as refrigerants, such as ammonia, chloromethane, and sulfur dioxide. Freon, in this case dichlorodifluoromethane, was invented by Thomas Midgley, Jr. with co-inventor Charles Kettering.³ Each Freon product is designated by a number; for instance, Freon-11 is trichlorofluoromethane, while Freon-12 is dichlorodifluoromethane.

DuPont began to phase out its production of Freon CFCs in the 1980s after federal regulatory agencies banned their use because they harm the Earth's ozone layer.⁴

In the 1990s, most uses of Freon chlorofluorocarbons (CFCs) were phased out.

The Montreal Protocol on Substances that Deplete the Ozone Layer classifies Freon-11 and Freon-12 as Annex A substances and bans their production and consumption as of 1996.

The interim replacements for CFCs are hydrochlorofluorocarbons (HCFCs), which contain chlorine that depletes stratospheric ozone, but to a much lesser extent than CFCs.⁵ Ultimately, hydrofluorocarbons (HFCs) will replace HCFCs with essentially no ozone destruction (although all three groups of halocarbons are powerful greenhouse gases). DuPont began producing hydrofluorocarbons as alternatives to Freon in the 1980s. These included Suva refrigerants and Dymel propellants.⁶ Any of these gases that are used as refrigerants are designated by an "R-" number and colloquially known as "Freon", whether they are made by DuPont or another supplier.

On November 8, 2008, 20 people died and 21 were injured when suffocated by Freon Gas (used in fire suppressant system) on board the Russian submarine K-152 Nerpa when the vessel's extinguishing systems unexpectedly activated during trials.

References

See also

• Haloalkane, a group of chemical compounds
• List of refrigerants
• Montreal Protocol

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